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β-Boron or β-silicon effect enables a regioselective Ni-catalyzed hydrocyanation of internal alkynes
DOI: 10.1039/D6GC00727A, PaperZhi-Hao Chen, Shuang Lin, Xinman Kang, Jiawu Huang, Jiasheng Qian, Qingjiang Li, Honggen Wang
An Earth-abundant nickel-catalysed regioselective hydrocyanation of propargylic B(MIDA) or silane substrates with AIBN (2,2′-azobis(2-methylpropionitrile)) as a low-toxicity H–CN source is reported.
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Techno-economic analysis and carbon footprint assessment of gasification based green methanol production from diverse biomass residues in China
DOI: 10.1039/D6GC00523C, PaperWubin Yan, Yinan Feng, Hongxi Luo, Xiaonan Wang, Chuan Zhang
Through a process system model, techno-economic analysis, and life cycle assessment of various bio-methanol production pathways, this study provides insights for the development of the biomethanol industry in China.
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Sustainable room-temperature, water-driven conversion of CO₂ to graphitic carbon quantum dots on electride electrodes
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00266H, PaperRungkiat Nganglumpoon, Jiang Li, Krongkwan Poolboon, Nattha Lertsukprasert, Theerawat Waiyaka, Thanayuth Jongrungrotbaworn, Anuchida Charuchit, Weerachon Tolek, Natthasini Sakulkittimasak, Paisan Kittisupakorn, Jakkapat Seeyangnok, Udomsilp Pinsook, Hideo Hosono, Joongjai Panpranot
Converting CO₂ into valuable solid carbon offers the dual benefits of permanent sequestration and economic utility. Although CO₂ reduction via reactive hydrides to produce solid carbon is thermodynamically feasible under...
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DOI: 10.1039/D6GC00266H, PaperRungkiat Nganglumpoon, Jiang Li, Krongkwan Poolboon, Nattha Lertsukprasert, Theerawat Waiyaka, Thanayuth Jongrungrotbaworn, Anuchida Charuchit, Weerachon Tolek, Natthasini Sakulkittimasak, Paisan Kittisupakorn, Jakkapat Seeyangnok, Udomsilp Pinsook, Hideo Hosono, Joongjai Panpranot
Converting CO₂ into valuable solid carbon offers the dual benefits of permanent sequestration and economic utility. Although CO₂ reduction via reactive hydrides to produce solid carbon is thermodynamically feasible under...
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Plastic waste boosted plasma-assisted ammonia synthesis process from N2 and H2O
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00740F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wenping Li, Jinguang Hu, Hangtian Hu, Hui Zheng, Zheng Li, Aiguo Wang, Zhangxin Chen
Sustainable ammonia (NH3) synthesis under moderate conditions, powered by renewable electricity and with reduced CO2 emissions, is a promising alternative to the energy-intensive Haber–Bosch process. In this work, we developed...
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DOI: 10.1039/D6GC00740F, Communication
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Wenping Li, Jinguang Hu, Hangtian Hu, Hui Zheng, Zheng Li, Aiguo Wang, Zhangxin ChenSustainable ammonia (NH3) synthesis under moderate conditions, powered by renewable electricity and with reduced CO2 emissions, is a promising alternative to the energy-intensive Haber–Bosch process. In this work, we developed...
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Unlocking Vanadium Diboride As High-Performance Cathodes for Zinc-Ion Batteries
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01404F, PaperYilei He, Lehuan Huang, Zining Li, Yang Li, Liubing Dong
Aqueous zinc-ion batteries (ZIBs) are increasingly valued for safe, large-scale and green energy storage applications. However, conventional Mn-based and V-based cathode materials suffer from inferior structure stability and poor conductivity-induced...
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DOI: 10.1039/D6GC01404F, PaperYilei He, Lehuan Huang, Zining Li, Yang Li, Liubing Dong
Aqueous zinc-ion batteries (ZIBs) are increasingly valued for safe, large-scale and green energy storage applications. However, conventional Mn-based and V-based cathode materials suffer from inferior structure stability and poor conductivity-induced...
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Sustainable Organic Electrochemistry: Earth-Abundant Metals (EAMs) in Organic Electrocatalysis
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00988C, Tutorial ReviewNajoua Sbei, Seyfeddine Rahali, Nisar Ahmed
The global shift toward sustainable chemical processes has accelerated interest in organic electrosynthesis as a green, electricity-driven alternative to traditional redox transformations. Among emerging catalytic systems, earth-abundant metals (EAMs) such...
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DOI: 10.1039/D6GC00988C, Tutorial ReviewNajoua Sbei, Seyfeddine Rahali, Nisar Ahmed
The global shift toward sustainable chemical processes has accelerated interest in organic electrosynthesis as a green, electricity-driven alternative to traditional redox transformations. Among emerging catalytic systems, earth-abundant metals (EAMs) such...
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Techno-economic assessment of sustainable isoprene production coupled with carbon dioxide sequestration using genetically engineered Synechococcus elongatus UTEX 2973
DOI: 10.1039/D5GC06199G, PaperIndrajeet Yadav, Akhil Rautela, Agendra Gangwar, Preeti Yadav, Sanjay Kumar
Engineered cyanobacteria use flue gas as a CO2 source to produce isoprene. A techno-economic analysis assesses commercial viability and determines the major cost factors influencing the overall production efficiency and scalability.
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Cellulosic ethylene glycol-economic potential, contaminants and process concepts
DOI: 10.1039/D6GC01055E, Perspective
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Jean-Paul Lange, Romolo Di Sabatino, M. Pilar RuizProducing ethylene glycol from lignocellulose requires effective and affordable removal of contaminants. Which are the troublesome contaminants and how to deal with them?
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Active lignin stabilization in lignocellulosic biomass fractionation: mechanisms and advancements
DOI: 10.1039/D6GC00829A, Critical Review
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Andreas Schröder, Ruijie Wu, Patrik Eklund, Henrik Grénman, Chunlin XuLignin condensation reduces lignin reactivity, increases structural heterogeneity, and limits efficient valorization. Condensation inhibition strategies preserve key linkages, promote depolymerization, and enhance downstream utilization of lignin.
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Mild-depolymerized lignin for reinforced polyvinyl alcohol wood adhesives
DOI: 10.1039/D6GC01017B, PaperRong Tan, Shuang-Lin Zou, Ying-Chun Xu, Jia-Hui Wang, Peng Zhu, Qiang Wang, Gui-Xia Zhang, Chang-You Shao, Ji Zhao, Lu Zheng, Ling-Ping Xiao, Run-Cang Sun
Mildly controlled depolymerization yields lignin-PVA adhesives with low formaldehyde emission, exceptional UV resistance, solvent stability, and high bonding strength for eco-friendly wood bonding.
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A well-defined Pd(II)-NHC aqua complex for ambient Buchwald–Hartwig amination in tert-butanol
DOI: 10.1039/D6GC00831C, PaperYaxu Liu, Zheng Wang, Ziyi Quan, Fengze Sun, Lixing Zhao, Lei Guo, Yixuan Gao, Bo Wang
A well-defined Pd(BIAN-IPr#)Cl2(OH2) catalyst enables efficient C–N cross-couplings with high chemoselectivity.
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Lignin and phenylenediamine synergy in carbon dots: deciphering the origin of long-wavelength photoluminescence and the carbon core growth
DOI: 10.1039/D6GC00520A, PaperKai Chen, Yongsheng Zhang, Tao Shi, Zhi-Min Zhao, Zhi-Hua Liu, Li Xu, Junbo Gong, Bing-Zhi Li
Hybrid carbon dots exhibit an evolution mechanism wherein a p-phenylenediamine-derived red fluorophore provides high quantum yield, and lignin forms a robust carbon core, enabling superior long-wavelength photoluminescence and photostability.
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Interfacially engineered MXene hydrogels with dual-conductive networks for high-performance multifunctional sensing via a green and sustainable strategy
DOI: 10.1039/D5GC06447C, PaperRunfeng Zhang, Yan Zhang, Zongmao Lv, Hai Yu, Jie Liu, Xuejing Zheng, Keyong Tang
The development of high-performance conductive hydrogels through green and sustainable strategies remains a pivotal challenge in flexible electronics.
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Sustainable production of high-energy-density fuels with natural terpenes and phenols
DOI: 10.1039/D5GC06600J, PaperJia Li, Yan-Hong Tan, Yan-Cheng Hu, Hong-Yan Wang, Jing-Pei Cao
Phenol, which can be sourced from lignin, serves as an effective coupling partner in ring-increasing reactions with terpenes. This approach enables the synthesis of polycyclic fuel candidates with improved energy density.
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Synergistic co-upcycling of polycarbonate and organophosphate ester wastes via chemically complementary reactivity
DOI: 10.1039/D6GC01199C, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yunkai Yu, Zexiang Wu, Minghao Zhang, Siyu Zhang, Yanwen Wang, Jing Li, Weixiang Wu, Qingqing MeiChemically complementary co-upcycling of polycarbonate plastics and organophosphate ester wastes into high-value bisphenol A alkyl ethers.
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A bioinspired photoenzymatic cascade enabled by a bifunctional arylformamidase for efficient synthesis of L-kynurenine derivatives
DOI: 10.1039/D6GC00950F, PaperChangmei Liu, Xiaorui Chen, Chengyue Miao, Changtong Zhu, Meiling Liu, Min He, Xinpeng Lu, Wenrui Huang, Yijian Rao, Zhenbo Yuan
A bioinspired one-pot one-step photoenzymatic cascade integrating a metal-free photocatalyst and an engineered bifunctional arylformidase directly convert L-Trp and its esters into L-Kyn under mild conditions with excellent green metrics evaluation.
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Green ionic liquid engineering for efficient and stable radioactive iodine capture: a review of the fundamentals and future perspectives
DOI: 10.1039/D5GC06740E, Critical ReviewXin Xin, Cheng Tang, Ling-Qiong Gou, Ling He, Guo-Hong Tao
The strong intramolecular hydrogen bond of curcumin is broken by ionization and curcumin anions form a weaker intermolecular hydrogen bond, which is easily disrupted, making it easy to react with iodine and form a new strong halogen bond.
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Low-Temperature Photothermal CO2-to-CO Conversion from Flue Gas Using a g-C3N4/TiO2/MXene Heterojunction with 100% Selectivity
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00125D, PaperYang Meng, Wen Li, Silvia Zamponi, Yongpeng Ma, Weifeng Zhou, Hongxia Chao, Shi Tang, Mario Berrettoni, Hongzhong Zhang
Via a sol-gel route, we synthesized a ternary type-II/Schottky heterojunction g-C3N4/TiO2/MXene (GTM) photothermal catalyst that harnessed residual heat from industrial flue gas together with sunlight to achieve efficient CO2 reduction...
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DOI: 10.1039/D6GC00125D, PaperYang Meng, Wen Li, Silvia Zamponi, Yongpeng Ma, Weifeng Zhou, Hongxia Chao, Shi Tang, Mario Berrettoni, Hongzhong Zhang
Via a sol-gel route, we synthesized a ternary type-II/Schottky heterojunction g-C3N4/TiO2/MXene (GTM) photothermal catalyst that harnessed residual heat from industrial flue gas together with sunlight to achieve efficient CO2 reduction...
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Catalyst-Free Lignin Photothermal Valorization via Promoted Aromatic C-H Cleavage
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC06859B, PaperZipeng Chen, Yifei Sun, Yunjie Zou, Sanli Tang, Jingjing Tian, Chengliang Mao, Zhihui Ai
Chemical conversion offers a promising way to native lignin valorization, which serves as a sustainable alternative to petroleum-derived carbon and hydrogen sources. However, selective transformation of lignin using conventional thermochemical...
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DOI: 10.1039/D5GC06859B, PaperZipeng Chen, Yifei Sun, Yunjie Zou, Sanli Tang, Jingjing Tian, Chengliang Mao, Zhihui Ai
Chemical conversion offers a promising way to native lignin valorization, which serves as a sustainable alternative to petroleum-derived carbon and hydrogen sources. However, selective transformation of lignin using conventional thermochemical...
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Promotion of protein utilization from corn by-product via calcium-dependent growth stimulation of Streptomyces sp. SCUT-3
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00587J, PaperFu-Gen Zhang, Chu-yan Liang, Ming-Shu Zhang, Lei Wu, Can Qin, Zhi-Wei Li, Jun Dai, Wei Huang, Jun-jin Deng, Xiao-Chun Luo
Calcium signaling plays fundamental roles in growth and development in plants and animals, yet its functional significance in prokaryotes remains poorly understood. In this study, calcium carbonate was identified as...
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DOI: 10.1039/D6GC00587J, PaperFu-Gen Zhang, Chu-yan Liang, Ming-Shu Zhang, Lei Wu, Can Qin, Zhi-Wei Li, Jun Dai, Wei Huang, Jun-jin Deng, Xiao-Chun Luo
Calcium signaling plays fundamental roles in growth and development in plants and animals, yet its functional significance in prokaryotes remains poorly understood. In this study, calcium carbonate was identified as...
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