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Biomass composition impacts the storage property of biocrude oil from hydrothermal liquefaction
DOI: 10.1039/D6GC00918B, PaperYingxian Wang, Maojiong Cao, Yuanhui Zhang, Zhidan Liu
Hydrothermal liquefaction of renewable resources produces biocrude. Feedstock biochemical composition affects its storage stability. Understanding the relationship between biocrude aging and biomass components enables shelf-life regulation.
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Electroreductive cross-electrophile coupling of polyfluoroarenes for the synthesis of polyfluoroarylmethanes and polyfluorinated biaryls
DOI: 10.1039/D5GC07014G, PaperYike Zhang, Shufei Zhu, Ling Fang, Chun Zhang, Dandan Hu, Jiacheng Wang, Jun-Qi Zhang, Youai Qiu, Hongjun Ren
A scalable noble-metal-free electroreductive cross-electrophile coupling method enables direct C–F functionalization of polyfluoroarenes to access polyfluoroarylmethanes and polyfluorinated biaryls with broad functional group tolerance.
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Upcycling poly(ε-caprolactone) into azepane via reductive ammonolysis over a titanium oxide-supported platinum catalyst
DOI: 10.1039/D6GC00098C, Communication
Open Access 
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Daratu E. K. Putri, Katsumasa Sakoda, Yoshiki Takamoto, Sho Yamaguchi, Takato Mitsudome, Tomoo MizugakiPoly(ε-caprolactone) (PCL) is selectively upcycled into azepane via reductive ammonolysis using a reusable Pt/TiO2 catalyst, offering a promising contribution to plastic upcycling and nitrogen-based circular economy strategies.
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Cu-based catalysts for efficient electrochemical nitrate reduction to ammonia
DOI: 10.1039/D5GC06700F, Tutorial ReviewYifei Wei, Yong-Chao Zhang, Yingnan Wang, Xiaoke Yang, Jinting Wu, Zhi-Jun Zuo, Yicheng Zhong, Guangbo Liu, Minghui Tan, Mingbo Wu
This review aims to provide not only a foundational reference for designing efficient Cu-based electrocatalysts but also a green chemistry-oriented roadmap for valorizing nitrate-containing wastewater into valuable ammonia.
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Solvent-free synthesis of renewable FDCA-based bis-cyclic carbonate using a metal-free heterogeneous catalyst
DOI: 10.1039/D5GC06663H, Paper
Open Access 
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Giovanni Berluti, Angelo Scopano, Gabriele Galletti, Edwin Otten, Coralie Jehanno, Paolo P. PescarmonaA new catalytic strategy was developed to synthesise a fully renewable bis-cyclic carbonate from dimethyl 2,5-furandicarboxylate and glycerol carbonate.
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Expanding the product spectrum in mixed-culture fermentation of organic solid waste through operational control
DOI: 10.1039/D5GC05638A, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hanna Prusak, Natalia Gutowska, Emilie Alaux, Mateusz Szczygiełda, Nay Yee Wint, Diana Z. Sousa, Mateusz Łężyk, Piotr Oleskowicz-PopielOperational control of pH, temperature, and retention time in OFMSW fermentation directs microbial community composition toward distinct carboxylate profiles, achieving selective production of caproate, succinate, or lactate.
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Synergistic Au–Pd catalysis of Sonogashira Couplings of Terminal Alkynes with Aryl Iodides in water
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00513F, CommunicationYilin Zhao, Zhangrong Lou, Zhenhua Fan, Masahiko Yamaguchi, Sheng Zhang, Ming Bao
The first example of synergistic Pd/Au catalysis of Sonogashira couplings in water is described. Using 0.01 mol% of a palladium catalyst in combination with 2 mol% of a gold cocatalyst,...
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DOI: 10.1039/D6GC00513F, CommunicationYilin Zhao, Zhangrong Lou, Zhenhua Fan, Masahiko Yamaguchi, Sheng Zhang, Ming Bao
The first example of synergistic Pd/Au catalysis of Sonogashira couplings in water is described. Using 0.01 mol% of a palladium catalyst in combination with 2 mol% of a gold cocatalyst,...
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Temperature-Controlled Divergent Reactions of Bicyclo[1.1.0] butanes with Thiocyanate-based Protic Ionic Liquids
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01320A, PaperPalash Roy, Rohan Chandra Das, Akkattu T. Biju
Bicyclo[1.1.0]butanes (BCBs), with their exceptional ring strain, serve as versatile precursors for complex molecular architectures, yet sustainable activation strategies remain limited. Herein, we report a protic ionic liquid (HMimNCS) that...
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DOI: 10.1039/D6GC01320A, PaperPalash Roy, Rohan Chandra Das, Akkattu T. Biju
Bicyclo[1.1.0]butanes (BCBs), with their exceptional ring strain, serve as versatile precursors for complex molecular architectures, yet sustainable activation strategies remain limited. Herein, we report a protic ionic liquid (HMimNCS) that...
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Direct Deoxygenative Sulfonylation of Free Alcohols Enabled by Triphenylphosphine EDA Complexes
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01725H, Communicationzhaoliang yang, haonan weng , yahao wang, shuo xu, yangmin cao, Mingming Yu, Zhen Wang, Yuan Zhou
Alkyl alcohols are widely used as bulk chemicals in industrial production and synthesis of high-value molecules, and there have been rapid advances in the transformation of alkyl alcohols to alkyl...
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DOI: 10.1039/D6GC01725H, Communicationzhaoliang yang, haonan weng , yahao wang, shuo xu, yangmin cao, Mingming Yu, Zhen Wang, Yuan Zhou
Alkyl alcohols are widely used as bulk chemicals in industrial production and synthesis of high-value molecules, and there have been rapid advances in the transformation of alkyl alcohols to alkyl...
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A Low-Energy and Air-stable Single-Atom Copper Catalyst for High Selectivity in Silaboration of Allenes
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00662K, CommunicationZeyu Ren, Liufan Wei, Qi Wu, Song Lin, Yigang Tang, Jin-Yu Chen, Mao-Rui Wang, Hai-Tao Tang, Fei-Hu Cui, Ying-Ming Pan
The practical application of Cu(I) single-atom catalysts (SACs) has been severely hampered by their inherent instability and the complexity of their synthesis. This work successfully developed an air-stable and recyclable...
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DOI: 10.1039/D6GC00662K, CommunicationZeyu Ren, Liufan Wei, Qi Wu, Song Lin, Yigang Tang, Jin-Yu Chen, Mao-Rui Wang, Hai-Tao Tang, Fei-Hu Cui, Ying-Ming Pan
The practical application of Cu(I) single-atom catalysts (SACs) has been severely hampered by their inherent instability and the complexity of their synthesis. This work successfully developed an air-stable and recyclable...
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Promoting H2O2 Production via Molten-Salt-Engineered Carbon Nitride Photocatalyst in a Triphasic Membrane Reactor
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01485B, PaperZirui You, chuyue lu, Jinpeng Hu, Xinxing Li, Jijia Sun, Yucong Huang, Fangrun Jin, Guanwu Lian, Wenguang Tu, Oleksandr Savateev, Jingjing Xiong, Dongxu Ji, Zhigang Zou, Zhongxin Chen
Scalable solar production of hydrogen peroxide (H2O2) is hampered by the sluggish diffusion kinetics and poor solubility of O2 in the aqueous solution. Herein, we integrate molten‑salt‑engineered carbon nitride (MS...
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DOI: 10.1039/D6GC01485B, PaperZirui You, chuyue lu, Jinpeng Hu, Xinxing Li, Jijia Sun, Yucong Huang, Fangrun Jin, Guanwu Lian, Wenguang Tu, Oleksandr Savateev, Jingjing Xiong, Dongxu Ji, Zhigang Zou, Zhongxin Chen
Scalable solar production of hydrogen peroxide (H2O2) is hampered by the sluggish diffusion kinetics and poor solubility of O2 in the aqueous solution. Herein, we integrate molten‑salt‑engineered carbon nitride (MS...
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Red Photon-Driven Aminomethylation of Indoles to Access the Sterically Hindered Indolyl Tertiary Amines
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00269B, PaperAslam C Shaikh, Nand Lal, Sanjay S. Bisht, Manoj V. Mane, Sarang Prakash Gumfekar
Introducing amine functionality to readily available feedstock chemicals is an effective strategy to rapidly enhance molecular complexity and access valuable scaffolds. Herein, we have developed a red photon-driven N-aminomethylation of...
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DOI: 10.1039/D6GC00269B, PaperAslam C Shaikh, Nand Lal, Sanjay S. Bisht, Manoj V. Mane, Sarang Prakash Gumfekar
Introducing amine functionality to readily available feedstock chemicals is an effective strategy to rapidly enhance molecular complexity and access valuable scaffolds. Herein, we have developed a red photon-driven N-aminomethylation of...
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Engineering a Thermally Localized Janus Membrane for Solar-assisted CO2 Desorption
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01331G, Paperwenqiang xu, qiuhui xie, Yiran Wu, Yang Ma, Tingting Shu, Ruizhe Wu, Jianjia Yu, Lusi Zou
While membrane reactors improve the energy efficiency of regenerating amine-based solvents, they do not overcome the inherently energy-intensive nature of the process. Herein, we present a novel solar-assisted CO2 stripping...
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DOI: 10.1039/D6GC01331G, Paperwenqiang xu, qiuhui xie, Yiran Wu, Yang Ma, Tingting Shu, Ruizhe Wu, Jianjia Yu, Lusi Zou
While membrane reactors improve the energy efficiency of regenerating amine-based solvents, they do not overcome the inherently energy-intensive nature of the process. Herein, we present a novel solar-assisted CO2 stripping...
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Warm Non-equilibrium Plasma-Assisted Catalysis for Sustainable Ammonia Synthesis
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00480F, CommunicationANANTHANARASIMHAN JAYANARASIMHAN, ABHISHEK UMESH SHETTY, DINESH DHANABAL, Sharanya Acharya, BHARGAVI KVSS, REETESH KUMAR GANGWAR, DEBAYAN SAHA, SHASHI RANJAN
Ammonia is synthesized mainly through energy intensive Haber–Bosch process, a major source of global CO₂ emissions, possesses difficulty to decentralize and utilize renewable electricity. Plasma assisted catalysis seems to be...
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DOI: 10.1039/D6GC00480F, CommunicationANANTHANARASIMHAN JAYANARASIMHAN, ABHISHEK UMESH SHETTY, DINESH DHANABAL, Sharanya Acharya, BHARGAVI KVSS, REETESH KUMAR GANGWAR, DEBAYAN SAHA, SHASHI RANJAN
Ammonia is synthesized mainly through energy intensive Haber–Bosch process, a major source of global CO₂ emissions, possesses difficulty to decentralize and utilize renewable electricity. Plasma assisted catalysis seems to be...
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Dual-site substitution enables high-voltage P2-Na0.67Ni0.33Mn0.67O2 cathodes with superior wide-temperature performance and enhanced ambient stability for sodium-ion batteries
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01005A, PaperXiangyu Wen, Haifeng Li, Jian Shi, Chao Yang, Zhongyi Fang, Fangzhou Zhao, Wanglai Cen, Yongzhi Zhang, Junke Ou
P2-type NaxNiyMnzO2 cathodes, while promising for rapid Na + transport, suffer from irreversible phase transitions, severe high-voltage degradation, and intrinsic hygroscopicity. To address these limitations, a synergistic doping strategy is...
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DOI: 10.1039/D6GC01005A, PaperXiangyu Wen, Haifeng Li, Jian Shi, Chao Yang, Zhongyi Fang, Fangzhou Zhao, Wanglai Cen, Yongzhi Zhang, Junke Ou
P2-type NaxNiyMnzO2 cathodes, while promising for rapid Na + transport, suffer from irreversible phase transitions, severe high-voltage degradation, and intrinsic hygroscopicity. To address these limitations, a synergistic doping strategy is...
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Machine learning boosted Design of Ionic Liquid-based Deep Eutectic Solvents for CO2 Capture
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00083E, Tutorial ReviewRuina Zhang, Guokai Cui, Guoxiong Zhan, Mengyi Ma, Xiaochun Zhang, Xiangping Zhang, Hanfeng Lu
The escalating atmospheric CO2 concentration demands sustainable and scalable carbon capture technologies. Deep eutectic solvents (DESs), especially those based on ionic liquids (ILs), offer a green and tunable alternative to...
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DOI: 10.1039/D6GC00083E, Tutorial ReviewRuina Zhang, Guokai Cui, Guoxiong Zhan, Mengyi Ma, Xiaochun Zhang, Xiangping Zhang, Hanfeng Lu
The escalating atmospheric CO2 concentration demands sustainable and scalable carbon capture technologies. Deep eutectic solvents (DESs), especially those based on ionic liquids (ILs), offer a green and tunable alternative to...
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Enhanced cleavage of C-C bonds in polycarbonate plastic wastes to valuable phenolics over potassium modified triazine-based strong base catalyst
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01312K, PaperXiaoqin Si, Yu Yue, Keke Niu, Hongyan Zhao, Guozhi Zhu, Xin Liu, Zhenfu Wang, Tianliang Lu
The recycling and upgrading of polycarbonate (PC) plastic wastes has attracted worldwide attention, while the selective cleavage of inert C-C bonds remains the key challenge. Herein, the noble metal-free potassium-modified...
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DOI: 10.1039/D6GC01312K, PaperXiaoqin Si, Yu Yue, Keke Niu, Hongyan Zhao, Guozhi Zhu, Xin Liu, Zhenfu Wang, Tianliang Lu
The recycling and upgrading of polycarbonate (PC) plastic wastes has attracted worldwide attention, while the selective cleavage of inert C-C bonds remains the key challenge. Herein, the noble metal-free potassium-modified...
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Genome scale reconstruction of lignin-derived aromatic catabolism across Pseudomonas enables modular chassis design for lignin bioconversion
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01067A, Critical ReviewRameez Khalid, Ayesha Muqadass, Huda Ahmad Alghamdi, Muhammad Zohaib Nawaz, Daochen Zhu
Pseudomonas is a metabolically versatile genus that has emerged as a promising chassis for upgrading lignin-derived aromatics, yet current knowledge remains fragmented across individual strains and pathways. Here, we synthesize...
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DOI: 10.1039/D6GC01067A, Critical ReviewRameez Khalid, Ayesha Muqadass, Huda Ahmad Alghamdi, Muhammad Zohaib Nawaz, Daochen Zhu
Pseudomonas is a metabolically versatile genus that has emerged as a promising chassis for upgrading lignin-derived aromatics, yet current knowledge remains fragmented across individual strains and pathways. Here, we synthesize...
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Electrochemical Ammonia Oxidation at Nickel Copper Hydroxide with H 2 Recovery at High Current Density and Selectivity
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC06877K, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dylan D. van Noordenne, Peter Jungbacker, Atsushi Urakawa, Fokko M. Mulder
Electrochemical conversion of ammonia has obtained increasing attention due to the potential applications for fertiliser production and wastewater treatment. This work demonstrates the application of a homogeneously copper-doped nickel hydroxide,...
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DOI: 10.1039/D5GC06877K, Paper
Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Dylan D. van Noordenne, Peter Jungbacker, Atsushi Urakawa, Fokko M. MulderElectrochemical conversion of ammonia has obtained increasing attention due to the potential applications for fertiliser production and wastewater treatment. This work demonstrates the application of a homogeneously copper-doped nickel hydroxide,...
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Efficient Preparation of Battery-Grade Li₂CO₃ from Spent Battery Leachate via Integrated Solvent Extraction and Direct Precipitation
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00941G, PaperQiyuan Zheng, Yanbin Yang, Wanting Xu, Jun Peng, Guiqing Zhang
The preparation of battery-grade Li₂CO₃ from spent lithium-ion battery leachates requires lengthy and costly multi-stage processes, including thermal evaporation, precipitation, carbonation, and thermal decomposition, resulting in significant lithium loss, high...
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DOI: 10.1039/D6GC00941G, PaperQiyuan Zheng, Yanbin Yang, Wanting Xu, Jun Peng, Guiqing Zhang
The preparation of battery-grade Li₂CO₃ from spent lithium-ion battery leachates requires lengthy and costly multi-stage processes, including thermal evaporation, precipitation, carbonation, and thermal decomposition, resulting in significant lithium loss, high...
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