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Dual hydrogen-buffer and interfacial spillover effects boosting bimetallic catalysts for mild-condition guaiacol hydrodeoxygenation

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC02407F, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Reem Shomal, Ying Zheng
A hydrogen-management strategy combining buffering, interfacial spillover, and bimetallic catalysis enables selective one-pot hydrodeoxygenation of lignin-derived phenolics under mild conditions.
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A Green and Scalable Mechanochemical Route to 2D Conductive Catecholate Metal–Organic Frameworks for Supercapacitor Application

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01243D, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Sharath Kandambeth, Binson Babu, Santosh K. Singh, Tahani A. Alrebdi, Kajal Uphade, Manuj Ahuja, Pranjit Barman
In this article, we report an ultrafast, green and scalable mechanochemical method for the synthesis of 2D conductive catecholate MOFs for energy storage applications. We found that the conventional solvothermal...
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Greening water-lean solvents for CO2 capture: replacing toxic 1-methyl-2-pyrrolidone with high-performance eco-friendly cosolvents

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10537-10547
DOI: 10.1039/D6GC02196D, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Huilin Li, Xuechong Ding, Teng Zhou
This work replaces reprotoxic NMP with eco-friendly solvents via large-scale screening, enabling sustainable, superior CO2 capture at lower energy cost.
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Integrating compartmentalized catalysis with low-energy recovery via a magneto-responsive water-in-water Pickering emulsion platform for sustainable biomanufacturing of 4-methyl-5-thiazoleethanol

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10510-10522
DOI: 10.1039/D6GC02039A, PaperWeizhi Huang, Xiaoqi Ding, Sha Ao, Huaqiang Cao, Jia Hu, Xiaoqing Han, Shilin Liu
Schematic illustration of magneto-responsive water-in-water Pickering emulsion for highly efficient 4-methyl-5-thiazoleethanol biosynthesis and magnetic separation of engineered bacteria to enable cyclic reuse of bacteria and nanoparticles.
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Reductive hydroformylation of linseed oil: from rhodium catalyst stability to machine learning data analysis

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10548-10556
DOI: 10.1039/D6GC02270G, PaperWalid Abdallah, Camille Galand, Michel Ferreira, Jérémy Ternel, Hervé Bricout, Sylvain Laclef, Serge Pilard, Adlane Sayede, Rachid Laref, Romdhane Karoui, Eliot Patrick Botosoa, Eric Monflier, Sébastien Tilloy
Robust catalytic system based on Rh/triethylamine enables reductive hydroformylation of linseed oil. Reaction optimization experiments and machine learning identified the key parameters controlling alcohol yield.
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Sustainable and selective carbene insertion into N–H bonds with a copper-bound recyclable surfactant under micellar conditions

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10472-10482
DOI: 10.1039/D6GC01787H, PaperShalini Kumari, Tanupriya Singh, Rajan Yadav, Pritesh Keshari, Susanta Hazra
Micellar confinement of a non-ionic designer surfactant, PAQ-750-M, stabilizes elusive Cu–carbene intermediates in water, enabling selective N–H bond insertion for accessing unnatural amino acid derivatives in water under mild conditions.
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Deep eutectic solvents for efficient and sustainable recycling of spent lithium-ion batteries: fundamental research, process intensification, and future prospects

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10308-10334
DOI: 10.1039/D6GC02403C, Critical ReviewYang Chen, Bi Luo, Jiangshuo Li, Xubiao Luo, Yefeng Zhou
The development of new energy vehicles has generated a surplus of spent lithium-ion batteries (LIBs), leading to an urgent need for recycling spent LIBs.
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Green extract-mediated synthesis of metallic nanoparticles assisted by ultrasound: a critical review for environmental applications

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10383-10408
DOI: 10.1039/D6GC00608F, Tutorial ReviewGabriel Toneto Druzian, Mariele Samuel Nascimento, Altevir Rossato Viana, Thiago Castanho Pereira, Fabio Andrei Duarte, Yang Tao, Erico Marlon Moraes Flores
In this review, the use of green extracts and ultrasound (US) for the synthesis of metallic nanoparticles (MNPs) for environmental applications is described, covering studies published from 2015 to 2025.
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Towards safe and sustainable ionic liquids: a critical outlook on industrial and pharmaceutical integration

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10350-10382
DOI: 10.1039/D6GC01231K, Tutorial ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Assya Bellaadem, Roland Kalb, Blaž Likozar, Filipa A. Vicente
An integrated assessment combining LCA, TEA, toxicity, and scalability provides a comprehensive evaluation of ionic liquids for industrial implementation.
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Development of sustainable green ink using agricultural biomass-derived green carbon: functional and environmental perspectives

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10447-10458
DOI: 10.1039/D6GC00729E, PaperRupam Bandyopadhyay, Rajarshi Bhar, Prakash Ajay Taksal, Jayanta Bhattacharya, Brajesh Kumar Dubey, Chandra Sekhar Tiwary
Agricultural biomass-derived green carbon substitutes fossil-derived carbon black ink, augmenting waterproof and antibacterial properties while reducing overall environmental impacts.
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Establishing parameters for resonant acoustic mixing (RAM) chemistry using Buchwald–Hartwig amination as a model

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, 28,10434-10446
DOI: 10.1039/D6GC00784H, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lori Gonnet, Cameron B. Lennox, Tristan H. Borchers, Mohammad S. Askari, Alexander Wahrhaftig-Lewis, Stefan G. Koenig, Karthik Nagapudi, Tomislav Friščić
Using Buchwald–Hartwig coupling as a model, this work uses reaction screening together with in situ monitoring to establish design parameters and explore safety in scaling of liquid-assisted RAM-based reactions. Laser beam image designed by Freepik.
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Low temperature semi-solid reaction route to Sm/Co-g-C3N4 single-atom catalyst: Tunable coupling effect between Sm and Co for boosting oxygen electrocatalysis

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC02044E, PaperDalong Li, Yunzhu Yang, Xinyi Bei, Jiayue Kang, Xinxin Zhu, Ting He, Zhichun Li, Guofeng Wang, Xiaobo He
Rechargeable Zn-air battery is a green energy conversion technique. It highly needs active bifunctional catalysts to promote sluggish cathodic oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) during the...
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Upcycling of Olive Waste Streams into High-Performance Biobased Epoxy Resins

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC02999J, PaperAbdelali Elasri, Mohcen Chahid, Florent Allais, Sami Fadlallah, Youssef Habibi
Olive mill wastewater (OMW), generated in vast quantities as a by-product of olive oil extraction, carries high concentrations of phenolic compounds, mainly hydroxytyrosol (HT), whose discharge into soil and water...
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How enzyme modifications influence sustainable CO2 fixation? A tradeoff between enzyme structures and functions

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC02548J, Critical ReviewOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Arnab Sil, Aaftaab Sethi, Diksha Dhiman, Meena Bisht, Gregory Franklin, Dibyendu Mondal
Rising atmospheric CO2 concentrations, driven by industrial activity and fossil fuel combustion, have intensified global climate challenges. Among various existing CO2 capture and conversion methods, the enzymatic approach stands out...
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Directed thermal decomposition of thermosetting epoxy resin in superheated steam: free radical-mediated mechanism and product regulation

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC02231F, PaperFurong Xie, Rong Chen, Chao Deng, Xiaoxin Li, Xi Ding, Danni Zhang, Guo-Ming Weng
Epoxy resin, as a widely used thermosetting material, faces significant challenges in efficient recycling and resource recovery after disposal. While our previous solvothermal work has made progress in epoxy resin...
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A corrosion-resistant green ionic liquid achieves near-zero wear at the interface with engineering steel

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC02522F, PaperMengjie Lin, Xia Zhang
In this study, several green ionic liquids (ILs) were synthesized, achieving virtually no wear on steel surfaces, with a wear rate of 2.26 × 10−10 mm3 N−1 m−1, representing a 99.8% reduction compared to the conventional green lubricant PEG.
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Etching reconstruction of ultrathin layered NiFe-hydroxide: building synergistic VFe(III)/Ni(III) active structures for an efficient urea oxidation reaction

Chemical News - 29 giugno, 2026 - 20:55

Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC01800A, PaperJinshan Liu, Miao Zhou, Yingying Chen, Xiaoping Liang, Zhifeng Liu
High-density cation vacancies rearrange Ni electrons, converting more Ni2+ into key active Ni3+ species, while promoting ultrathin structures that enlarge specific surface area and expose more active sites.
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Scalable electropolymerized microporous polymer films for solar light-driven reduction of atmospheric CO2 coupled with H2O2 production

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC02305C, PaperTingting Zhang, Xuyang Li, Waner Li, Youyu Meng, Jie Zhao, Junjie Liu, Chao Zeng, Bo Wang, Lixiang Zhong, Chunhui Dai
Large-area flexible polymer films with permanent porosity and appealing electronic properties are highly desirable for photocatalytic CO2 conversion. However, controllable manufacturing of polymer-based photocatalytic films for selective CO2 reduction remains...
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Wettability-Engineered Metal-Organic Frameworks: From Hydrophilic to Superhydrophobic Porous Interfaces for Green and Sustainable Processes in Humid Environments

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01822J, Critical ReviewNengxiu Zhu, Ruiying Wang, Mei Pan, Dianzeng Jia
With the increasing demand for green processes involving water utilization, humid air regulation, and environmental remediation, metal-organic frameworks (MOFs) have emerged as promising porous materials capable of operating under water-rich...
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A lignin β–β motif as a precursor to low-temperature fused-aromatic formation

Chemical News - 29 giugno, 2026 - 20:55
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC02344D, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Jiaqi Wang, Eiji Minami, Haruo Kawamoto
Lignin valorization is typically directed toward recoverable aromatic monomers, but carbon can also be diverted into fused aromatic and condensed products. Here, pinoresinol is used as a β–β model to...
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