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Dual-Strategy Guided Bioinspired Catalysts for Efficient Synthesis of Pyrazole Derivatives Via Hydrazide–Ketone Condensation
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC05414A, PaperYunfei Li, Wenhao Yu, Shuhua Li, Mo Xian, Yaojie Liu, Hao Lan, Zongjiang Yu, Long Jiang, Chao Xu
Pyrazole derivatives find widespread applications in fields such as pharmaceuticals. Their synthesis typically proceeds via a condensation-driven C–N bond coupling followed by a dehydration step. The condensation reaction mediated by...
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DOI: 10.1039/D5GC05414A, PaperYunfei Li, Wenhao Yu, Shuhua Li, Mo Xian, Yaojie Liu, Hao Lan, Zongjiang Yu, Long Jiang, Chao Xu
Pyrazole derivatives find widespread applications in fields such as pharmaceuticals. Their synthesis typically proceeds via a condensation-driven C–N bond coupling followed by a dehydration step. The condensation reaction mediated by...
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Expanding the product spectrum in mixed-culture fermentation of organic solid waste through operational control
DOI: 10.1039/D5GC05638A, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Hanna Prusak, Natalia Gutowska, Emilie Alaux, Mateusz Szczygiełda, Nay Yee Wint, Diana Z. Sousa, Mateusz Łężyk, Piotr Oleskowicz-PopielOperational control of pH, temperature, and retention time in OFMSW fermentation directs microbial community composition toward distinct carboxylate profiles, achieving selective production of caproate, succinate, or lactate.
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Selective Deuteroreduction of Alkynes by Zn/Mn with Nickel Catalysis under Mechanical Conditions
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC05935F, PaperXuejie Yang, Chong Zu, Tingrui Liu, Zixian Yang Yang, Jiegong Deng, yufei han, Wu Li, Bingnan Du
Selective deuteroreduction of alkynes remains a longstanding challenge, as semi-deuteration is often hampered by overreduction, while tetra-deuteration suffers from incomplete conversion. Herein, we report a mechanochemically driven nickel-catalyzed deuteroreduction of...
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DOI: 10.1039/D5GC05935F, PaperXuejie Yang, Chong Zu, Tingrui Liu, Zixian Yang Yang, Jiegong Deng, yufei han, Wu Li, Bingnan Du
Selective deuteroreduction of alkynes remains a longstanding challenge, as semi-deuteration is often hampered by overreduction, while tetra-deuteration suffers from incomplete conversion. Herein, we report a mechanochemically driven nickel-catalyzed deuteroreduction of...
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Piezocatalytic oxidation of lignin-derived phenol to p-benzoquinone: a sustainable route for green polymerization inhibitors
DOI: 10.1039/D5GC06083D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Xinlei Ma, Bo Zhang, Xin Huang, Qing Xu, Roger RuanThis study successfully synthesized MoS2 with different sulfur vacancy concentrations via a hydrothermal method for the piezocatalytic selective oxidation of phenol to p-benzoquinone (p-BQ).
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Trace electrolyte additives dynamically regulating the zinc anode interface towards stable zinc-based energy storage
DOI: 10.1039/D5GC06513E, PaperXinyu Yang, Ke Zhang, Liubing Dong
Glycolide is reported as a trace additive of the aqueous zinc-salt electrolyte to dynamically regulate the zinc deposition interface, realizing long-term stable zinc anodes.
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Electrochemical C(sp2)–H deuterodifluoromethylation of quinoxalinones and 2H-indazoles with CF2DSO2Na
DOI: 10.1039/D5GC05992E, PaperYuhang Ding, Xin Liu, Yanlin Wu, Meichao Li, Zhenlu Shen
In CH3CN/H2O solution, an electrochemical method for the deuterodifluoromethylation of quinoxalinones and 2H-indazoles was developed using CF2DSO2Na at 25 °C.
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Direct synthesis of cyclic carbonates from olefins and CO2 via ionic liquid catalysis with mutually promoting bifunctional groups
DOI: 10.1039/D5GC06239J, PaperLi-Feng Xu, Wen-Jun Xie, Shan-Shan Chen, Alexander O. Terent'ev, Hong-Ru Li, Liang-Nian He
With H2O2 as the oxidant, the bifunctional ionic liquid facilitated a two-step process for the synthesis of cyclic carbonate directly from olefins and CO2 in 90% yield obviating the need for transition metals.
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Semi-heterogeneous dual iron/photocatalytic decarboxylative C(sp3)–C(sp3) cross-coupling via radical sorting
DOI: 10.1039/D5GC05705A, PaperYajun Sun, Tengfei Kang, Yingdi Feng, Huaming Sun, Geyang Song, Dong Xue
An efficient decarboxylative C(sp3)–C(sp3) cross-coupling is achieved via a semi-heterogeneous dual iron/photocatalysis system with diverse radical precursors.
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Thiazole-Linked Covalent Organic Frameworks for Enhanced Photoreductive Gold Recovery from E-Waste
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC05287D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gilles Matthys, Andreas Laemont, Diem Van Hamme, Wafaa A. Mohamed, Laurens Bourda, Rundong Wang, Karen Leus, Nathalie De Geyter, Rino Morent, Roy Lavendomme, Pascal Van Der Voort
In this work we developed two different thiazole-linked Covalent Organic Frameworks (COFs) from their imine analogues for the recovery of gold from electronic waste. These gold ions are reduced through...
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DOI: 10.1039/D5GC05287D, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Gilles Matthys, Andreas Laemont, Diem Van Hamme, Wafaa A. Mohamed, Laurens Bourda, Rundong Wang, Karen Leus, Nathalie De Geyter, Rino Morent, Roy Lavendomme, Pascal Van Der VoortIn this work we developed two different thiazole-linked Covalent Organic Frameworks (COFs) from their imine analogues for the recovery of gold from electronic waste. These gold ions are reduced through...
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Heterogeneous Single-Site copper in Hierarchical MOF Microspheres Enables Sustainable Urea-Functionalization of Quinoline N-Oxides
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC05300E, PaperKaijian Liu, Song Yu, Yantao Zhou, Jiarui Guo, Zhuobin Yu, Jie Li, Yumin Ding, Jinhua Ou, Jinxuan Liu
Ureas are privileged scaffolds across drug discovery and materials science, yet their installation onto complex pharmacophores, such as quinoline derivatives, remains challenging due to the inherent limitations of conventional homogeneous...
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DOI: 10.1039/D5GC05300E, PaperKaijian Liu, Song Yu, Yantao Zhou, Jiarui Guo, Zhuobin Yu, Jie Li, Yumin Ding, Jinhua Ou, Jinxuan Liu
Ureas are privileged scaffolds across drug discovery and materials science, yet their installation onto complex pharmacophores, such as quinoline derivatives, remains challenging due to the inherent limitations of conventional homogeneous...
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Natural MOFs Enable Hydrogen Bonded Ion Highways for Solid State Batteries
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC06492A, PaperJie Li, Youliang Wang, Liequan Liu, xingtao Qi, Lingfeng Zhu, Chen Liu, Ningrui Zhan, Hai Zhang, Fan Wang, Ze Zhang, Zhenyu Yang
Solid-state batteries hold great promise for energy storage but remain constrained by the inherent trade-off between high ionic conductivity and interfacial stability in polymer electrolytes. Here, we introduce a natural,...
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DOI: 10.1039/D5GC06492A, PaperJie Li, Youliang Wang, Liequan Liu, xingtao Qi, Lingfeng Zhu, Chen Liu, Ningrui Zhan, Hai Zhang, Fan Wang, Ze Zhang, Zhenyu Yang
Solid-state batteries hold great promise for energy storage but remain constrained by the inherent trade-off between high ionic conductivity and interfacial stability in polymer electrolytes. Here, we introduce a natural,...
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Ultrafast Dissolution of Intact Wood via Deep Eutectic Solvent-Mediated Pathways
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC06371J, PaperEnqing zhu, Lili Zhang, Qing Zhang, Shaoning Wang, Xin Li, Zhengjun Shi, Jinxia Ma, Juan Yu, Muhammad Wajid Ullah, Khalid Ali Khan, Zhiguo Wang, Yimin Fan, Orlando J. Rojas
The efficient dissolution of large-sized plant fiber biomass remains a long-standing challenge due to its compact, multi-layered cell wall architecture. Here, we report a universal and energy-efficient two-step dissolution strategy...
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DOI: 10.1039/D5GC06371J, PaperEnqing zhu, Lili Zhang, Qing Zhang, Shaoning Wang, Xin Li, Zhengjun Shi, Jinxia Ma, Juan Yu, Muhammad Wajid Ullah, Khalid Ali Khan, Zhiguo Wang, Yimin Fan, Orlando J. Rojas
The efficient dissolution of large-sized plant fiber biomass remains a long-standing challenge due to its compact, multi-layered cell wall architecture. Here, we report a universal and energy-efficient two-step dissolution strategy...
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Glycerol electrolytes for safer and more sustainable sodium ion batteries
DOI: 10.1039/D5GC05621G, Communication
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Zachary T. Gossage, Teppei Furuichi, Tomooki Hosaka, Kei Shibuya, Shinichi KomabaGlycerol jumps to the front as an extremely low-cost, green solvent to replace toxic and flammable solvents used in batteries.
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Palladium-catalyzed asymmetric sequential hydroalkylation and hydroamination of 1,3-enynes with 3-hydroxyindoles
DOI: 10.1039/D5GC05558J, Paper
Open Access
  This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Qiuyu Li, Ruixue Wu, Tianbao Wu, Renkang Wei, Zhijiao Li, Shang Gao, Minyan Wang, Hequan Yao, Aijun LinAn unprecedented Pd-catalyzed asymmetric sequential hydroalkylation/hydroamination of 1,3-enynes was developed. This method provides efficient access to chiral pyrido[1,2-a]indoles and derivatives in good yields with excellent enantioselectivities.
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Photoredox-catalyzed cascade difluoromethylation/SO2 reintegration/polyfluoroarylation of conjugated dienes with a bifunctional CF2HSO2Na reagent
DOI: 10.1039/D5GC05765E, PaperKehan Jiao, Yunliang Guo, Jiuli Xia, Kaixuan Chen, Lihan Zhu, Ying Dong, Jiao Qu, Guangfan Zheng, Jiaqiong Sun, Tao Xiong, Qian Zhang
A visible-light-driven, photoredox-catalyzed difluoromethylation, SO2 reintegration, and polyfluoroarylation cascade of conjugated dienes has been developed, employing CF2HSO2Na as a bifunctional reagent and polyfluoroarenes as terminating agents.
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Chloride molten salt-mediated one-step electrochemical recycling of tellurium from copper(Ⅰ) telluride
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC06339F, PaperLibo Chen, Jiguo Tu, Meng Zhang, Mingyin Kou, Shuqiang Jiao
Copper(Ⅰ) telluride (Cu2Te) from copper smelting process is an important source of tellurium (Te) recovery. However, conventional Te extraction relies on acid- and alkaline-leaching processes, which generate toxic waste and...
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DOI: 10.1039/D5GC06339F, PaperLibo Chen, Jiguo Tu, Meng Zhang, Mingyin Kou, Shuqiang Jiao
Copper(Ⅰ) telluride (Cu2Te) from copper smelting process is an important source of tellurium (Te) recovery. However, conventional Te extraction relies on acid- and alkaline-leaching processes, which generate toxic waste and...
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Obituary: Roger Arthur Sheldon (1942–2025)
DOI: 10.1039/D5GC90241J, Obituary
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Martyn Poliakoff, Ben L. FeringaTo cite this article before page numbers are assigned, use the DOI form of citation above.
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Photochemical upcycling of polystyrene waste by BiCl3
DOI: 10.1039/D5GC05996H, CommunicationS. Srividya, Apurba Kumar Pal, K. Geetharani
We report photo-oxidative upcycling of polystyrene to benzoic acid via LMCT of a main group catalyst, BiCl3, which is commercially available and inexpensive. This additive-free reaction proceeds under mild conditions using oxygen as the sole oxidant.
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Embedded carbon dot mediator in a Ce-MoO3−x heterojunction for improved visible-light-driven N2 fixation: performance and interfacial activation mechanism
DOI: 10.1039/D5GC06146F, PaperHuaiwei Zhang, Liang Bao, Ying Pan, Lulu Xu, Wei Wang
This work advances green chemistry by developing an all-solid-state heterostructure for improved nitrogen photo-fixation performances, offering a sustainable route to access valuable ammonia.
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Techno-Economic Insights into Ammonia as a Hydrogen Vector: Synthesis, Cracking, Storage, and Supply Chain Solutions
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC04925C, Tutorial ReviewMousumi Biswas, Shankab Phukan, SURAJ GOSWAMI, Jit Satra, Gaurav Gupta, Tarun Yadav, Ranjith Krishna Pai, Manas Roy, Somenath Garai
Amid the global energy crisis, green hydrogen emerges as a potent energy carrier, yet the hydrogen economy grapples with economic viability, low volumetric energy density, storage, and safety issues that...
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DOI: 10.1039/D5GC04925C, Tutorial ReviewMousumi Biswas, Shankab Phukan, SURAJ GOSWAMI, Jit Satra, Gaurav Gupta, Tarun Yadav, Ranjith Krishna Pai, Manas Roy, Somenath Garai
Amid the global energy crisis, green hydrogen emerges as a potent energy carrier, yet the hydrogen economy grapples with economic viability, low volumetric energy density, storage, and safety issues that...
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