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Dielectric layer induces depolarization field and interfacial interaction evolution to stabilize Zn anodes
DOI: 10.1039/D6GC01133K, PaperYiqun Du, Anbin Hu, Huidi Shi, Ning Li, Yang Zhou, Jinkai Li, Bingqiang Cao
The NaNbO3 dielectric interphase regulates polarization field and interfacial interactions, suppressing Zn dendrites and the HER, thereby enabling durable aqueous Zn batteries.
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Light-powered sequential manipulation of microalgal lipid bioprocessing via an artificial photoactive membrane antenna
DOI: 10.1039/D5GC06459G, PaperYihui Shen, Bing Liu, Gongmeiyue Su, Hang Yao, Zhao Li, Lei Han, Chengcheng Zhou
We have developed a programmable biohybrid that integrates lipid accumulation and extraction into a solar-driven workflow for sustainable biodiesel production.
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Self-powered aluminium batteries for sustainable water treatment: performance, mechanisms, and techno-economic assessment
DOI: 10.1039/D6GC00439C, Critical ReviewYiqi Tang, Zupei Wang, Weiwei Du, Xiangjie Ma, Haochuan Lin, Huanhuan Tang, Hong Yao, Xinyang Li
This review summarizes recent advances in such systems across electrocoagulation, desalination, in situ H2O2 generation, and integrated bioelectrochemical applications, with emphasis on performance, mechanisms, and techno-economic feasibility.
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A robust and efficient heterogeneous MoS2/Al2O3 catalyst for the hydrogenative recycling of polyurethane waste
DOI: 10.1039/D6GC00699J, PaperCongxue Yuan, Shuang Cao, Liang Chen, Ruitong Gao, Yajing Duan, Hui Du
This study successfully achieved near-complete depolymerization of real polyurethane waste using a reusable MoS2/Al2O3 catalyst without base addition.
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Harnessing deep eutectic solvents and mesoporous silica nanosphere immobilization for supercharged amine dehydrogenase catalysis in continuous flow
DOI: 10.1039/D6GC01106C, PaperWeixi Kong, Biao Li, Qi Zhang, Xuyang Lei, Ke Zheng, Xiaoyang Yue, Yunting Liu, Yanjun Jiang
Blocking a detrimental helix-to-loop transition by a betaine–acetic acid DES enhances engineered AmDH activity and stability, while immobilization and flow operations further augment these effects, enabling intensified ARA at high substrate loads.
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Efficient and selective recovery of spent NCM cathode materials: a green deep eutectic solvent process via synergistic acidity–viscosity regulation
DOI: 10.1039/D6GC01210H, PaperGuangke Ye, Guofan Zhang, Yunxia Wu
TL-DES leaches >95% NCM metals at 100 °C. Ethanol precipitates Ni/Co fully, Mn 60%, leaves Li+, forming LDH precursor. LCA: 0.52 kg CO2 eq kg−1, 7.22 MJ kg−1.
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Lignin -based hydrogels through a green-metrics lens: solvents, crosslinking chemistries, and scalable processes
DOI: 10.1039/D5GC06795B, Critical ReviewDegang Meng, Ashenafi Berhanu, Vinod Kumar, Farhan Ahmad, Weike Li, He Gao, Daochen Zhu
Dynamic and antifreezing lignin-based materials can be fabricated through several network-forming strategies, including dynamic covalent crosslinking, metal–phenolic coordination, enzyme-mediated crosslinking, and visible-light-induced polymerization.
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Safe and Sustainable by Design: Case Study of a Magnetic Torus Microreactor and Bionanocompounds for Wastewater Treatment
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D5GC06437F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Olga P. Fuentes, Amaimen Guillén-Pacheco, Johann F. Osma, Guido W Sonnemann
The Safe and Sustainable by Design (SSbD) framework provides a structured approach to integrate safety, environmental, social, and economic considerations into early-stage technological innovation. While SSbD has been applied to...
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DOI: 10.1039/D5GC06437F, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Olga P. Fuentes, Amaimen Guillén-Pacheco, Johann F. Osma, Guido W SonnemannThe Safe and Sustainable by Design (SSbD) framework provides a structured approach to integrate safety, environmental, social, and economic considerations into early-stage technological innovation. While SSbD has been applied to...
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AI-driven, self-optimizing electrochemical flow platform for rapid synthesis of 2-amino substituted benzothiazole libraries
DOI: 10.1039/D6GC02164F, PaperKuldeep Singh Bhati, Abhilash Rana, Ruchi Chauhan, Ajay K. Singh, Siddharth Sharma
This work presents an autonomous electrochemical flow platform that enables efficient oxidant-free construction of benzothiazoles, highlighting a sustainable approach to heterocycle generation.
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High-rate mass transfer in a mesoporous catalyst with atomically dispersed cobalt sites enables efficient electrochemical synthesis of glycine
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00863A, PaperXiaoxia Yu, Ke Chang, Juan Peng
To replace toxic, cumbersome conventional routes, green electrosynthesis of glycine is a hotspot. However, due to the complexity of multi‑electron/proton transfer, simultaneous attainment of high Faradaic efficiency (FE) and high...
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DOI: 10.1039/D6GC00863A, PaperXiaoxia Yu, Ke Chang, Juan Peng
To replace toxic, cumbersome conventional routes, green electrosynthesis of glycine is a hotspot. However, due to the complexity of multi‑electron/proton transfer, simultaneous attainment of high Faradaic efficiency (FE) and high...
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In-Situ Carbon Recovery from Refractory Organics in Wastewater: A Critical Review
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC01352J, Critical ReviewNing Li, Rui Wang, Jianhui Zhao, Xiaoming Peng, Wenchao Peng, Beibei Yan, Guanyi Chen
Industrial wastewater containing refractory organic pollutants poses serious ecological and public health risks. Conventional mineralization technologies face challenges of carbon emissions and inefficient carbon utilization. Emerging in-situ carbon recovery systems...
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DOI: 10.1039/D6GC01352J, Critical ReviewNing Li, Rui Wang, Jianhui Zhao, Xiaoming Peng, Wenchao Peng, Beibei Yan, Guanyi Chen
Industrial wastewater containing refractory organic pollutants poses serious ecological and public health risks. Conventional mineralization technologies face challenges of carbon emissions and inefficient carbon utilization. Emerging in-situ carbon recovery systems...
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Ultrasound-assisted catalytic valorization of nitric acid waste to ammonia using hydrogen nanobubbles
Green Chem., 2026, Accepted Manuscript
DOI: 10.1039/D6GC00304D, PaperHee Sun Park, Han-Bok Seo, Heung Bin Hwi Lim, Seung-Yop Lee, Nam Hur
The sustainable conversion of nitric acid waste into ammonia offers a dual benefit of wastewater remediation and green ammonia synthesis. Here we report an ultrasound-assisted catalytic process that efficiently converts...
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DOI: 10.1039/D6GC00304D, PaperHee Sun Park, Han-Bok Seo, Heung Bin Hwi Lim, Seung-Yop Lee, Nam Hur
The sustainable conversion of nitric acid waste into ammonia offers a dual benefit of wastewater remediation and green ammonia synthesis. Here we report an ultrasound-assisted catalytic process that efficiently converts...
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A Type III porous liquid with high separation performance for linear/branched C4 olefin mixtures
DOI: 10.1039/D6GC00330C, PaperQiuwei Ma, Bei Liu, Chun Deng, Jie Zhang, Changyu Sun, Yun-Lei Peng, Guangjin Chen
A new Type III porous liquid integrates the molecular sieving mechanism of CALF-20M with the fluidity of the sterically hindered solvent 1,3-dimethyl-2-imidazolidinone, enabling highly selective separation of linear/branched C4 olefins.
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Electroreduction of aryl diazonium salts: a sustainable strategy for organic synthesis
DOI: 10.1039/D6GC01132B, Tutorial ReviewXing Ji, Tao Zhou, Zi-Wei Duan, Hai-Tao Tang, Ying-Ming Pan
This review covers electrochemical reduction of aryl diazonium salts to aryl and diazonium radicals for C–H functionalization and C–C/C-heteroatom bond formation, summarizing recent advances, mechanisms, and green synthesis applications.
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Boosting photocatalytic H2O2 evolution through synergistic sulfur doping and crystalline engineering of carbon nitride
DOI: 10.1039/D6GC01234E, PaperYumeng Qi, Meiyu Xu, Shuting Deng, Bo Wang, Shijie Wang, Wei Zhou
One-step pyrolyzed sulfur-doped crystalline carbon nitride synergistically boosts charge separation, light harvesting, and O2 activation for superior photocatalytic H2O2 production.
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Co-immobilization of enzymes and cofactors enabled by liquid–liquid phase separation for continuous-flow catalysis
DOI: 10.1039/D6GC00150E, CommunicationChuyi Xiao, Zhiyong Luo, Yuyao Wan, Kaihui Xu, Xingyuan Fang, Dingyi Yang, Ting Guo, Hao Yuan, Tao Meng
A carrier-free continuous-flow catalytic system based on LLPS co-immobilizes enzymes and cofactors in an all-aqueous environment, enabling self-sufficient biocatalysis with excellent activity and stability.
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Defect-engineered Ru–Co/TiO2−x catalysts for highly efficient plasma-catalytic ammonia synthesis under ambient conditions
DOI: 10.1039/D6GC00524A, PaperBianbian Gao, Yutong Feng, Chunyu Li, Jiantao Zhao, Yitian Fang, Guoqiang Cao
Plasma-catalytic ammonia synthesis offers a promising route toward decentralized and sustainable NH3 production under mild conditions.
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Metal-free, scalable synthesis of degradable polyester resins for high-resolution DLP 3D printing via organoboron-catalyzed ROCOP
DOI: 10.1039/D6GC00136J, PaperJiahao Liu, Meichen Liu, Jie Li, Yujiao Li, Chunwang Yi
Our work advances additive manufacturing by developing a polyester resins via organoboron-catalyzed. The high-resolution printed parts were successfully realized via thiol–ene photopolymerization with a tetrathiol crosslinker.
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Depolymerized lignin as an enabler for superior lignin–acrylonitrile copolymers for sustainable wet-spun fibers
DOI: 10.1039/D6GC01695B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Talita Nascimento, Marta Ramos-Andrés, Marta C. Lourenço, Ana C. MarquesControlled lignin depolymerization enables the organic solvent-free aqueous synthesis of linear, high-molecular-weight copolymers, successfully processed into sustainable continuous wet-spun fibers.
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Deep eutectic solvents as recyclable solvent–electrolyte systems for electroreductive C–O cleavage of lignin models
DOI: 10.1039/D5GC05226B, Paper
Open Access
  This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Astrid Kjær Steffensen, Helena Lundberg, Anders RiisagerDeep eutectic solvents (DESs), formed from hydrogen bonding acceptors and donors, are investigated as recyclable solvent–electrolyte systems and found promising as medium for electroreductive cleavage of C–O bonds in lignin model ethers.
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