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Substrate tunnel redesign of short-chain dehydrogenase enabled efficient biocatalytic production of the TRPV1 antagonist trans-4-tert-butylcyclohexanol

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4130-4142
DOI: 10.1039/D5GC06523B, PaperTing Wang, Lidan Ye, Hongwei Yu
Redesign of the short-chain dehydrogenase UCPA via tunnel engineering for biocatalytic production of trans-4-tert-butylcyclohexanol with high activity and diastereoselectivity.
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Optimal design of decentralized ammonia production via electric Haber–Bosch systems

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4103-4118
DOI: 10.1039/D5GC06782K, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Lorenzo Rosa, Davide Tonelli
Decentralized, electrified Haber–Bosch ammonia can reduce supply risks but is costly today. Optimization across six countries shows competitiveness emerging by 2045, driven by cheaper renewables, flexible reactors, and efficient, dynamic green chemistry designs.
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Ethanol-aerosol-derived in situ syngas roasting for lithium recovery from spent layered oxide cathodes

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC06185G, PaperHengjun Tai, Yan Li, Wentao Li, Chengming Du, Chengzong Li, Tao Li
Ethanol-aerosol-assisted roasting strategy: integrating selective Li recovery with in situ syngas generation.
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A hydrophobic ionic liquid and ZIF-8 co-modified graphene oxide membrane for efficient osmotic energy conversion

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4092-4102
DOI: 10.1039/D5GC06269A, PaperYizhuo Wang, Changchao Yan, Jingyun Guo, Zhizhen Ye, Xinyi Wan, Xinsheng Peng
A GO/ZIF-8/[Bmim][NTf2] composite membrane was prepared via a confined strategy, which exhibits excellent cation selectivity, high power density and good stability.
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Ethanol-assisted mechanochemical synthesis of MOF-199-derived CuOx/carbon composites with tunable copper species for photo-enhanced Fenton-like dye degradation

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4075-4091
DOI: 10.1039/D5GC05389G, PaperKhoa D. Tran, Hoan T. Phan, Khoa A. Nguyen, Khoa A. N. Van, Ha V. Le, Huy X. Le, Phuoc H. Ho, Ha P. K. Huynh, Khoa D. Nguyen
An ethanol-assisted mechanochemical route enables the synthesis of MOF-199 and its transformation into CuOx/carbon composites with tunable copper species for efficient visible-light-enhanced Fenton-like dye degradation.
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Sustainable diamine synthesis via continuous-flow reductive amination over a stable Re1Ox–Ni interface

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC06288H, PaperJiaxiang Qin, Tongtong Feng, Jiachen Wang, Wen Cui, Amol Amrute, Xiaoling Mou, Li Yan, Shibo Xi, Ronghe Lin, Javier Pérez-Ramírez, Yunjie Ding
Halogen-free continuous-flow DMDEE synthesis with a high yield and commercial-grade purity enabled by atomically dispersed Re1Ox–Ni interfaces via reductive amination of diethylene glycol and morpholine.
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Inverse ZrO2/Co catalysts enable robust and efficient glucose hydrogenation

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, Advance Article
DOI: 10.1039/D6GC00137H, PaperJinhao Qian, Haoan Fan, Shiyu Wang, Wenhua Zhou, Yilei Ren, Chao Chen, Zhenyu Zhang, Jie Fu
Robust glucose hydrogenation is achieved by an inverse 5ZrO2/Co catalyst with abundant Zr–OV–Co sites.
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Constructing Ru–O–Nb interfaces in RuOx/NbOPO4 nanosheets for the one-pot conversion of lignin-derived phenol and benzyl alcohol to polycycloalkane aviation biofuels

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC06219E, PaperDanni Liu, Kaige Zhang, Wenli Zhao, Xiaopo Niu, Xiangwen Zhang, Qingfa Wang
The one-pot solvent-free synthesis of sustainable high-density polycycloalkane biofuels using 3%RuOx/NbOPO4 from lignin-derived phenol and benzyl alcohol.
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Biomass-derived highly graphitized hard carbon materials via tandem carbonization–graphitization for high-performance sodium-ion batteries

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,3884-3895
DOI: 10.1039/D5GC06092C, PaperTianqi Cao, Guanyu Zhang, Zengjian Guo, Jiarui Zhu, Ge Kong, Xuesong Zhang, Lujia Han
Biomass-derived hard carbons featuring coexisting pseudo-graphitic domains and closed pores were synthesized via a combined carbonization–graphitization strategy, enabling high potential as high-performance anodes for sodium-ion batteries.
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Constructing a Ca-rich protective layer on the anode for high-performance aqueous zinc-ion batteries

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, Advance Article
DOI: 10.1039/D5GC06296A, PaperLun Zhang, Zhuo Chen, Junrun Feng, Hao Gu, Lin Sheng, Zhangxiang Hao, Feng Ryan Wang
A biocompatible calcium-rich protective layer (Ca10(OH)2(PO4)6, CHP) is constructed on zinc anodes, effectively suppressing dendrite growth and side reactions. The Zn@CHP symmetric cell achieves an ultralong lifespan of 1180 h at 5 mA cm−2.
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Progress of photothermal/thermal catalytic CO2 hydrogenation by metal-modified CeO2

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,3455-3485
DOI: 10.1039/D5GC05746A, Tutorial ReviewHuiqing Dong, Ziyi Zhang, Dongxu Zhou, Siyu Huang, Zhuopeng Lin, Xiaodong Zhang, Zhongxiao Zhang, Jianqiu Lei, Ning Liu
The graphical abstract illustrates CO2 hydrogenation via photothermal and thermal catalysis over noble and non-noble metal-modified CeO2 to produce valuable chemicals.
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Fully sustainably sourced and closed-loop recyclable underwater adhesive for on-demand erasable electronic sealing

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,3696-3708
DOI: 10.1039/D5GC06477E, PaperXingle Chen, Zexuan Wang, Mingsong Huang, Qin Zhang, Xin Liu
In this work, a fully sustainably sourced and closed-loop recyclable electronic adhesive is designed and exhibits tough bonding behavior, on-demand erasability, and recyclability in various harsh environments.
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Correction: The hydrogen economy fairytale

Chemical News - 2 marzo, 2026 - 20:39
Green Chem., 2026, 28,3896-3896
DOI: 10.1039/D6GC90021F, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Tycho Ehrhardt, Gadi Rothenberg
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Solvent-free aerobic oxidation of benzylic C–H bonds via nanoconfined cobalt–porphyrin frameworks: a green and safe catalytic strategy

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4173-4187
DOI: 10.1039/D6GC00073H, PaperHong-liang Ye, Kai-jing Zhang, Yuan-bin She
The solvent-free aerobic oxidation of inert benzylic C–H bonds using molecular oxygen represents an atom-economical and environmentally benign route to high-value oxygenated chemicals.
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Itaconic acid as a platform chemical for bio-based polymers: from green polymerization strategies to structure-driven applications

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,3371-3393
DOI: 10.1039/D5GC06410D, Critical ReviewXueying Liu, Florent Allais, Sami Fadlallah
As a promising bio-based platform chemical, itaconic acid (IA) combines two carboxyl groups with an activated vinyl group, enabling extensive derivatization and multiple polymerization pathways.
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Quaternary ammonium hydroxide-catalyzed methanolysis of bisphenol–A polycarbonate: performance, mechanism, and scale-up

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4263-4276
DOI: 10.1039/D5GC05255F, PaperLu Zhang, Li Song, Haipeng Dong, Jing-Bang Kang, Honglu Zhu, YunJin Zhong, Hengcong Tao, Yao-Yao Zhang, Xianming Zhang
Tetramethylammonium hydroxide presents an efficient PC depolymerization catalyst, showing good activity and selectivity with favorable chromatic properties and no need for post-reaction removal, enabling seamless implementation at the pilot scale.
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Selective conversion of lignin to benzoquinones under ambient conditions: unlocking the potential of a single platform chemical strategy

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4255-4262
DOI: 10.1039/D5GC04121J, PaperXinquan Li, Anthony J. Chavez, Hao Zhang, Daria Andryushkina, Peter C. Ford, Mahdi M. Abu-Omar
Lignin, a highly abundant component of lignocellulosic biomass, represents a promising sustainable source of aromatic platform chemicals.
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Modulation of hydrogen transfer behaviors over Fe/Cu interfacial sites for a boosted electrocatalytic nitrate reduction reaction

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4277-4291
DOI: 10.1039/D5GC06182B, PaperHongxia Luo, Lin Gu, Ziyang Wu, Jun Chen, Jianping Yang
Fe/Cu heterointerface dual-sites modulate *H transfer over Cu/FeOOH, enabling *H transfer from Fe to Cu to accelerate *NO2  deoxygenation/hydrogenation, yielding superior NO3RR activity and stability.
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Well-controlled synthesis of biodegradable polyesters using edible catalysts

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,4243-4254
DOI: 10.1039/D5GC05933J, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Toshiki Miwa, Ryota Suzuki, Tianle Gao, Takuya Yamamoto, Feng Li, Takuya Isono, Toshifumi Satoh
Edible catalysts, including organic acids and their sodium or potassium salts, have been demonstrated to enable the well-controlled synthesis of biodegradable polyesters, which are environmentally friendly and biomedical polymer materials. Image modified using Google Gemini.
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Dual-strategy guided bioinspired catalysts for efficient synthesis of pyrazole derivatives via hydrazide–ketone condensation

Chemical News - 2 marzo, 2026 - 20:39

Green Chem., 2026, 28,3614-3627
DOI: 10.1039/D5GC05414A, PaperYunfei Li, Wenhao Yu, Shuhua Li, Mo Xian, Yaojie Liu, Hao Lan, Zongjiang Yu, Long Jiang, Chao Xu
Dual-strategy guided design enables the development of artificial enzyme catalysts capable of highly efficient catalysis of non-native substrates, such as pyrazole-derived compounds.
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